At the heart of any atomic clock are two quantum states in an atom or ion, which have an energy difference that is well-defined (typ. associated with long lifetimes of the involved quantum states) and that is minimally effected by the environment. The transition between these states is called “clock transition”, can be investigated spectroscopically, and serves as reference for a “local oscillator” or “flywheel”. The local oscillator (laser or microwave, depending on the transition energy) is frequency-stabilized to the clock transition and provides stable oscillating electromagnetic radiation: This is called atomic frequency standard. Counting the oscillations of the frequency standard (e.g. one “tick” corresponds to one cycle of that oscillation) one can then realize an atomic time standard.
Traditional microwave atomic clocks rely on microwave transitions in cesium (Cs) or rubidium (Rb). Cs is actually used to define time itself: “One second is the time it takes for a 9,192,631,770 oscillations of a frequency standard stabilized to the transition between the two mF=0 hyperfine ground states of 133Cs.”. While microwave atomic clocks have served us well, their fundamental limitation lies in the relatively low frequency of the reference transition and the impact of environment-induced perturbations.
Optical atomic clocks instead use transitions in the optical domain at much higher frequencies of several 1014 Hz. Typical versions use thermal atoms (e.g. two-photon Rb clocks or high resolution spectroscopy of iodine) and have similar limits like another type of clocks that use microwave transitions in laser-cooled and trapped atoms or ions. We refer to the latter ones as “microwave quantum clocks” due to the use of quantum technologies for laser-cooling and trapping. Both of these clock types reach relative uncertainties of 10-14 to (rarely) below 10-15 (in case of Cs atomic fountain clocks).
The most advanced clocks and in terms of uncertainty and accuracy are “optical quantum clocks”. They combine laser-cooling and trapping of atoms or ions (hence quantum technologies) with optical clock transitions. The result is a vastly improved uncertainty down to 10-18 and below. Careful analyses of environmental influences, potential errors, and corrections allow for relative accuracies on the order of 10-18.
The two leading architectures of are: optical lattice clocks with neutral atoms and optical clocks with trapped ions.